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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages.

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Title: New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages.
Alternate Title: We report here the synthesis, structure, luminescence, and magnetic properties of three new cage-like tetranuclear silsesquioxanes (Et4N)2[(PhSiO1..5)8(Y0.75Dy0.25O1.5)4(O)(NO2.5)6(EtOH)2(MeCN)2] and (Cat)2[(PhSiO1.5)8(DyO1.5)4(O)(NO2.5)6(EtOH)2(MeCN)2] (Cat=Et4N or Ph4P). They present a characteristic green-yellow emission. The Y3+/Dy3+ compound displays in addition a field-induced Single Molecule Magnet (SMM) behavior making it the first reported
Authors: Kulakova, Alena N.1,2,3, Nigoghossian, Karina3, Félix, Gautier3, Khrustalev, Victor N.2,4, Shubina, Elena S.1, Long, Jérôme3 joulia.larionova@umontpellier.fr, Guari, Yannick3, Carlos, Luis D.5, Bilyachenko, Alexey N.1,2 bilyachenko@ineos.ac.ru, Larionova, Joulia3
Source: European Journal of Inorganic Chemistry. 7/22/2021, Vol. 2021 Issue 27, p2696-2701. 6p.
Database: Academic Search Ultimate
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  Data: New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages.
– Name: TitleAlt
  Label: Alternate Title
  Group: TiAlt
  Data: We report here the synthesis, structure, luminescence, and magnetic properties of three new cage-like tetranuclear silsesquioxanes (Et4N)2[(PhSiO1..5)8(Y0.75Dy0.25O1.5)4(O)(NO2.5)6(EtOH)2(MeCN)2] and (Cat)2[(PhSiO1.5)8(DyO1.5)4(O)(NO2.5)6(EtOH)2(MeCN)2] (Cat=Et4N or Ph4P). They present a characteristic green-yellow emission. The Y3+/Dy3+ compound displays in addition a field-induced Single Molecule Magnet (SMM) behavior making it the first reported
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  Data: <searchLink fieldCode="AR" term="%22Kulakova%2C+Alena+N%2E%22">Kulakova, Alena N.</searchLink><relatesTo>1,2,3</relatesTo><br /><searchLink fieldCode="AR" term="%22Nigoghossian%2C+Karina%22">Nigoghossian, Karina</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Félix%2C+Gautier%22">Félix, Gautier</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Khrustalev%2C+Victor+N%2E%22">Khrustalev, Victor N.</searchLink><relatesTo>2,4</relatesTo><br /><searchLink fieldCode="AR" term="%22Shubina%2C+Elena+S%2E%22">Shubina, Elena S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Long%2C+Jérôme%22">Long, Jérôme</searchLink><relatesTo>3</relatesTo><i> joulia.larionova@umontpellier.fr</i><br /><searchLink fieldCode="AR" term="%22Guari%2C+Yannick%22">Guari, Yannick</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Carlos%2C+Luis+D%2E%22">Carlos, Luis D.</searchLink><relatesTo>5</relatesTo><br /><searchLink fieldCode="AR" term="%22Bilyachenko%2C+Alexey+N%2E%22">Bilyachenko, Alexey N.</searchLink><relatesTo>1,2</relatesTo><i> bilyachenko@ineos.ac.ru</i><br /><searchLink fieldCode="AR" term="%22Larionova%2C+Joulia%22">Larionova, Joulia</searchLink><relatesTo>3</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22European+Journal+of+Inorganic+Chemistry%22">European Journal of Inorganic Chemistry</searchLink>. 7/22/2021, Vol. 2021 Issue 27, p2696-2701. 6p.
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=asn&AN=151995603
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        Value: 10.1002/ejic.202100308
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      – TitleFull: New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages.
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              Text: 7/22/2021
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