Vibrational structure in C 1s photoelectron spectra of ethylene on the Si(1 0 0)(2 × 1) surface

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Title: Vibrational structure in C 1s photoelectron spectra of ethylene on the Si(1 0 0)(2 × 1) surface
Authors: Yamashita, Y. yyama@issp.u-tokyo.ac.jp, Machida, S.1, Nagao, M.1, Yamamoto, S.1, Mukai, K.1, Yoshinobu, J.1
Source: Chemical Physics Letters. Jun2003, Vol. 374 Issue 5/6, p476. 6p.
Subjects: Ethylene, Photoelectron spectroscopy, Vibrational spectra
Abstract: We have investigated the C 1s photoelectron spectra of ethylene on the Si(1 0 0)(2 × 1) surface, using high resolution photoelectron spectroscopy. The vibrational structure has been observed in the C 1s spectra where the C–H stretching mode is dominant. The vibrational splittings of C 1s ionized state are very similar to those in the ground state. It is found that linear coupling model is applicable in this system and this excitation process is a Frank–Condon process. The curvature of potential energy surface of C–H and C–D bond is almost unchanged upon core ionization. [Copyright &y& Elsevier]
Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Vibrational structure in C 1s photoelectron spectra of ethylene on the Si(1 0 0)(2 × 1) surface
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  Data: <searchLink fieldCode="AR" term="%22Yamashita%2C+Y%2E%22">Yamashita, Y.</searchLink><i> yyama@issp.u-tokyo.ac.jp</i><br /><searchLink fieldCode="AR" term="%22Machida%2C+S%2E%22">Machida, S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Nagao%2C+M%2E%22">Nagao, M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yamamoto%2C+S%2E%22">Yamamoto, S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Mukai%2C+K%2E%22">Mukai, K.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yoshinobu%2C+J%2E%22">Yoshinobu, J.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Physics+Letters%22">Chemical Physics Letters</searchLink>. Jun2003, Vol. 374 Issue 5/6, p476. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Ethylene%22">Ethylene</searchLink><br /><searchLink fieldCode="DE" term="%22Photoelectron+spectroscopy%22">Photoelectron spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Vibrational+spectra%22">Vibrational spectra</searchLink>
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  Label: Abstract
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  Data: We have investigated the C 1s photoelectron spectra of ethylene on the Si(1 0 0)(2 × 1) surface, using high resolution photoelectron spectroscopy. The vibrational structure has been observed in the C 1s spectra where the C–H stretching mode is dominant. The vibrational splittings of C 1s ionized state are very similar to those in the ground state. It is found that linear coupling model is applicable in this system and this excitation process is a Frank–Condon process. The curvature of potential energy surface of C–H and C–D bond is almost unchanged upon core ionization. [Copyright &y& Elsevier]
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  Group: Ab
  Data: <i>Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/S0009-2614(03)00732-2
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        Text: English
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      – SubjectFull: Vibrational spectra
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              Text: Jun2003
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