Electrical and humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole doped with both KOH and K2CO3 salts.

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Title: Electrical and humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole doped with both KOH and K2CO3 salts.
Authors: Su, Pi-Guey1 spg@ulive.pccu.edu.tw, Syu, Hong-Ci1
Source: Sensors & Actuators B: Chemical. Mar2017, Vol. 240, p595-603. 9p.
Subjects: Carboxylic acids, Doping agents (Chemistry), Potassium hydroxide, Electric impedance, Composite materials
Abstract: Novel impedance-type humidity sensors were made of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole that was doped with KOH and K 2 CO 3 salts. The humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole were improved by doping with two alkali salts (KOH and K 2 CO 3 ), whose dissociation constants differed greatly from each other. The electrical properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole that was doped with KOH or a mixture of KOH and K 2 CO 3 were examined in detail and found to be functions of relative humidity (RH). Additionally, the effects of the salts on the sensing properties (linearity and sensitivity) were elucidated. The sensor that was made of the 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole/KOH/K 2 CO 3 composite film exhibited favorable impedance, high sensitivity, good linearity, small hysteresis, a short response/recovery time, a weak dependence on temperature and high long-term stability over the humidity range studied. The sensing mechanism of the 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole/KOH/K 2 CO 3 composite film was elucidated using impedance plots. [ABSTRACT FROM AUTHOR]
Copyright of Sensors & Actuators B: Chemical is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Electrical and humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole doped with both KOH and K2CO3 salts.
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  Data: <searchLink fieldCode="AR" term="%22Su%2C+Pi-Guey%22">Su, Pi-Guey</searchLink><relatesTo>1</relatesTo><i> spg@ulive.pccu.edu.tw</i><br /><searchLink fieldCode="AR" term="%22Syu%2C+Hong-Ci%22">Syu, Hong-Ci</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Sensors+%26+Actuators+B%3A+Chemical%22">Sensors & Actuators B: Chemical</searchLink>. Mar2017, Vol. 240, p595-603. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Carboxylic+acids%22">Carboxylic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Doping+agents+%28Chemistry%29%22">Doping agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Potassium+hydroxide%22">Potassium hydroxide</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+impedance%22">Electric impedance</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink>
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  Data: Novel impedance-type humidity sensors were made of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole that was doped with KOH and K 2 CO 3 salts. The humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole were improved by doping with two alkali salts (KOH and K 2 CO 3 ), whose dissociation constants differed greatly from each other. The electrical properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole that was doped with KOH or a mixture of KOH and K 2 CO 3 were examined in detail and found to be functions of relative humidity (RH). Additionally, the effects of the salts on the sensing properties (linearity and sensitivity) were elucidated. The sensor that was made of the 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole/KOH/K 2 CO 3 composite film exhibited favorable impedance, high sensitivity, good linearity, small hysteresis, a short response/recovery time, a weak dependence on temperature and high long-term stability over the humidity range studied. The sensing mechanism of the 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole/KOH/K 2 CO 3 composite film was elucidated using impedance plots. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Sensors & Actuators B: Chemical is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.snb.2016.09.027
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      – Code: eng
        Text: English
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        PageCount: 9
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      – SubjectFull: Carboxylic acids
        Type: general
      – SubjectFull: Doping agents (Chemistry)
        Type: general
      – SubjectFull: Potassium hydroxide
        Type: general
      – SubjectFull: Electric impedance
        Type: general
      – SubjectFull: Composite materials
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      – TitleFull: Electrical and humidity-sensing properties of 1-(4-carboxylic acid phenyl)-2,5-dimethyl-1H-pyrrole doped with both KOH and K2CO3 salts.
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            NameFull: Su, Pi-Guey
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            NameFull: Syu, Hong-Ci
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              M: 03
              Text: Mar2017
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              Y: 2017
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              Value: 240
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