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Applying the protective CuMn2O4 spinel coating on AISI-430 ferritic stainless steel used as solid oxide fuel cell interconnects.

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Title: Applying the protective CuMn2O4 spinel coating on AISI-430 ferritic stainless steel used as solid oxide fuel cell interconnects.
Authors: Ranjbar-Nouri, Z.1, Soltanieh, M.1 mansour_soltanieh@iust.ac.ir, Rastegari, S.1
Source: Surface & Coatings Technology. Jan2018, Vol. 334, p365-372. 8p.
Subjects: Ferritic steel, Solid oxide fuel cells, Evaporation (Chemistry), Electroplating, Heat treatment, Current density (Electromagnetism)
Abstract: Ferritic stainless steels at high temperature and long operating time of solid oxide fuel cells (SOFC) face with some problems such as overgrowth and spallation of the surface oxide and cathode poisoning due to chromium evaporation. In the present work in order to improve the above-mentioned problems, the protective/conductive CuMn 2 O 4 spinel coating was created on the AISI-430 ferritic stainless steel by means of pulse electrodeposition and subsequent heat treatment. Therefore, at first, the copper was applied to the substrate from a sulfate bath with an average current density of 48 mA/cm 2 and a deposition time of 4 min. Subsequently, manganese was electrodeposited on the copper layer from a sulfate bath with an average current density of 125 mA/cm 2 and a deposition time of 8 min. The frequency and duty cycle in the pulse electrodeposition of Cu and Mn Were considered100 Hz and 80%, respectively. Then, to convert the metallic layers to spinel and also to evaluate its prevention of outward diffusion of Cr, oxidation was carried out at 750 °C in the air for 24 h and 100 h. Microstructural evaluation of samples cross-section by scanning electron microscope (SEM) equipped with EDS indicated that the CuMn 2 O 4 spinel layer acted as a barrier to outward diffusion of Cr effectively and the amount of Cr in the coating surface was zero. Also, coating layer had good adhesion to the substrate. By investigation of samples oxidation in the air for 0.5, 10 and 120 min at 750 °C, the results indicated that Mn was rapidly oxidized to MnO and Mn 3 O 4 , at the outset of the oxidation of the Cu Mn metallic coating. Gradually, the MnO and Mn 3 O 4 disappeared and Mn 2 O 3 was formed and the copper was oxidized to CuO. Finally, spinel phase of CuO and Mn 2 O 3 was formed. [ABSTRACT FROM AUTHOR]
Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Applying the protective CuMn2O4 spinel coating on AISI-430 ferritic stainless steel used as solid oxide fuel cell interconnects.
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  Label: Abstract
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  Data: Ferritic stainless steels at high temperature and long operating time of solid oxide fuel cells (SOFC) face with some problems such as overgrowth and spallation of the surface oxide and cathode poisoning due to chromium evaporation. In the present work in order to improve the above-mentioned problems, the protective/conductive CuMn 2 O 4 spinel coating was created on the AISI-430 ferritic stainless steel by means of pulse electrodeposition and subsequent heat treatment. Therefore, at first, the copper was applied to the substrate from a sulfate bath with an average current density of 48 mA/cm 2 and a deposition time of 4 min. Subsequently, manganese was electrodeposited on the copper layer from a sulfate bath with an average current density of 125 mA/cm 2 and a deposition time of 8 min. The frequency and duty cycle in the pulse electrodeposition of Cu and Mn Were considered100 Hz and 80%, respectively. Then, to convert the metallic layers to spinel and also to evaluate its prevention of outward diffusion of Cr, oxidation was carried out at 750 °C in the air for 24 h and 100 h. Microstructural evaluation of samples cross-section by scanning electron microscope (SEM) equipped with EDS indicated that the CuMn 2 O 4 spinel layer acted as a barrier to outward diffusion of Cr effectively and the amount of Cr in the coating surface was zero. Also, coating layer had good adhesion to the substrate. By investigation of samples oxidation in the air for 0.5, 10 and 120 min at 750 °C, the results indicated that Mn was rapidly oxidized to MnO and Mn 3 O 4 , at the outset of the oxidation of the Cu Mn metallic coating. Gradually, the MnO and Mn 3 O 4 disappeared and Mn 2 O 3 was formed and the copper was oxidized to CuO. Finally, spinel phase of CuO and Mn 2 O 3 was formed. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Surface & Coatings Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.surfcoat.2017.11.036
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      – Code: eng
        Text: English
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        PageCount: 8
        StartPage: 365
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      – SubjectFull: Ferritic steel
        Type: general
      – SubjectFull: Solid oxide fuel cells
        Type: general
      – SubjectFull: Evaporation (Chemistry)
        Type: general
      – SubjectFull: Electroplating
        Type: general
      – SubjectFull: Heat treatment
        Type: general
      – SubjectFull: Current density (Electromagnetism)
        Type: general
    Titles:
      – TitleFull: Applying the protective CuMn2O4 spinel coating on AISI-430 ferritic stainless steel used as solid oxide fuel cell interconnects.
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            NameFull: Ranjbar-Nouri, Z.
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            NameFull: Soltanieh, M.
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            NameFull: Rastegari, S.
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            – D: 25
              M: 01
              Text: Jan2018
              Type: published
              Y: 2018
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