Uptake/release of organic contaminants by microplastics: A critical review of influencing factors, mechanistic modeling, and thermodynamic prediction methods.

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Title: Uptake/release of organic contaminants by microplastics: A critical review of influencing factors, mechanistic modeling, and thermodynamic prediction methods.
Authors: Mosca Angelucci, Domenica1 (AUTHOR), Tomei, M. Concetta1 (AUTHOR)
Source: Critical Reviews in Environmental Science & Technology. 2022, Vol. 52 Issue 8, p1356-1400. 45p.
Subjects: Microplastics, Pollutants, Micropollutants, Forecasting, Food chains, Prediction models
Abstract: The role of microplastics (MPs) as a vector of chemicals is generally recognized: a wide range of micropollutants have been detected in MPs sampled in different environmental compartments, and, due to their ubiquitous distribution, they can be transferred through aquatic and terrestrial organisms into the food chain. Providing representative models is challenging due to the intrinsic dynamic evolution characterizing the natural phenomena, which cannot be adequately investigated in lab experiments. On the other side, simulation/prediction tools are strongly required because of the long time-scale characterizing the MPs' persistence in the environment. This article provides a review of the updated literature on mechanistic models and predictive thermodynamic methods applied (or applicable), to describe the uptake/release processes of pollutants by MPs. Intrinsic and environmental factors influencing the process kinetics and the equilibrium distribution are discussed in detail. Mechanistic models and thermodynamic prediction methods are analyzed and their potentialities for application to MPs highlighted with specific examples. Finally, a critical analysis of the limitations related to the simplifying assumptions in modeling and to the representativeness of the lab-scale data is performed to evaluate their effects on the reliability of the predictions and to identify knowledge gaps and address future research needs. [ABSTRACT FROM AUTHOR]
Copyright of Critical Reviews in Environmental Science & Technology is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Uptake/release of organic contaminants by microplastics: A critical review of influencing factors, mechanistic modeling, and thermodynamic prediction methods.
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  Data: <searchLink fieldCode="AR" term="%22Mosca+Angelucci%2C+Domenica%22">Mosca Angelucci, Domenica</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tomei%2C+M%2E+Concetta%22">Tomei, M. Concetta</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Critical+Reviews+in+Environmental+Science+%26+Technology%22">Critical Reviews in Environmental Science & Technology</searchLink>. 2022, Vol. 52 Issue 8, p1356-1400. 45p.
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  Data: <searchLink fieldCode="DE" term="%22Microplastics%22">Microplastics</searchLink><br /><searchLink fieldCode="DE" term="%22Pollutants%22">Pollutants</searchLink><br /><searchLink fieldCode="DE" term="%22Micropollutants%22">Micropollutants</searchLink><br /><searchLink fieldCode="DE" term="%22Forecasting%22">Forecasting</searchLink><br /><searchLink fieldCode="DE" term="%22Food+chains%22">Food chains</searchLink><br /><searchLink fieldCode="DE" term="%22Prediction+models%22">Prediction models</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The role of microplastics (MPs) as a vector of chemicals is generally recognized: a wide range of micropollutants have been detected in MPs sampled in different environmental compartments, and, due to their ubiquitous distribution, they can be transferred through aquatic and terrestrial organisms into the food chain. Providing representative models is challenging due to the intrinsic dynamic evolution characterizing the natural phenomena, which cannot be adequately investigated in lab experiments. On the other side, simulation/prediction tools are strongly required because of the long time-scale characterizing the MPs' persistence in the environment. This article provides a review of the updated literature on mechanistic models and predictive thermodynamic methods applied (or applicable), to describe the uptake/release processes of pollutants by MPs. Intrinsic and environmental factors influencing the process kinetics and the equilibrium distribution are discussed in detail. Mechanistic models and thermodynamic prediction methods are analyzed and their potentialities for application to MPs highlighted with specific examples. Finally, a critical analysis of the limitations related to the simplifying assumptions in modeling and to the representativeness of the lab-scale data is performed to evaluate their effects on the reliability of the predictions and to identify knowledge gaps and address future research needs. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Critical Reviews in Environmental Science & Technology is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1080/10643389.2020.1856594
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 45
        StartPage: 1356
    Subjects:
      – SubjectFull: Microplastics
        Type: general
      – SubjectFull: Pollutants
        Type: general
      – SubjectFull: Micropollutants
        Type: general
      – SubjectFull: Forecasting
        Type: general
      – SubjectFull: Food chains
        Type: general
      – SubjectFull: Prediction models
        Type: general
    Titles:
      – TitleFull: Uptake/release of organic contaminants by microplastics: A critical review of influencing factors, mechanistic modeling, and thermodynamic prediction methods.
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            NameFull: Mosca Angelucci, Domenica
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            NameFull: Tomei, M. Concetta
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              Text: 2022
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              Y: 2022
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