Bibliographic Details
| Title: |
Solvothermal Synthesis of BiCuI5(phen)2, a Novel Metal–Organic Halobismuthate. |
| Authors: |
Hines, Adrian T.1 (AUTHOR), Morrison, Gregory1 (AUTHOR), Smith, Mark D.1 (AUTHOR), zur Loye, Hans-Conrad1 (AUTHOR) zurLoye@mailbox.sc.edu |
| Source: |
Journal of Chemical Crystallography. Sep2022, Vol. 52 Issue 3, p394-398. 5p. |
| Subjects: |
Single crystals, Crystal structure, Space groups, X-ray diffraction, Crystal growth, Ethanol |
| Abstract: |
Crystals of the title compound BiCuI5(phen)2 were synthesized solvothermally by reacting CuCl2·2H2O, Bi(NO3)3·5H2O, NH4I, and 1,10-phenanthroline in an ethanol/water solvent mixture. BiCuI5(phen)2 crystallizes in the monoclinic space group P21/n. The asymmetric unit consists of a [Bi2I10] iodobismuthate group and a [CuI(phen)2] complex that are linked via a shared iodine. In this paper, we describe the synthesis and single crystal structure of the new metal–organic halobismuthate complex, BiCuI5(phen)2. X-ray diffraction quality single crystals of a novel metal–organic halobismuthate, BiCuI5(phen)2 were grown in water/ethanol solvent mixture at 120 °C and used for structure determination using single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
