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Solvothermal Synthesis of BiCuI5(phen)2, a Novel Metal–Organic Halobismuthate.

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Title: Solvothermal Synthesis of BiCuI5(phen)2, a Novel Metal–Organic Halobismuthate.
Authors: Hines, Adrian T.1 (AUTHOR), Morrison, Gregory1 (AUTHOR), Smith, Mark D.1 (AUTHOR), zur Loye, Hans-Conrad1 (AUTHOR) zurLoye@mailbox.sc.edu
Source: Journal of Chemical Crystallography. Sep2022, Vol. 52 Issue 3, p394-398. 5p.
Subjects: Single crystals, Crystal structure, Space groups, X-ray diffraction, Crystal growth, Ethanol
Abstract: Crystals of the title compound BiCuI5(phen)2 were synthesized solvothermally by reacting CuCl2·2H2O, Bi(NO3)3·5H2O, NH4I, and 1,10-phenanthroline in an ethanol/water solvent mixture. BiCuI5(phen)2 crystallizes in the monoclinic space group P21/n. The asymmetric unit consists of a [Bi2I10] iodobismuthate group and a [CuI(phen)2] complex that are linked via a shared iodine. In this paper, we describe the synthesis and single crystal structure of the new metal–organic halobismuthate complex, BiCuI5(phen)2. X-ray diffraction quality single crystals of a novel metal–organic halobismuthate, BiCuI5(phen)2 were grown in water/ethanol solvent mixture at 120 °C and used for structure determination using single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Chemical Crystallography is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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  Data: <searchLink fieldCode="DE" term="%22Single+crystals%22">Single crystals</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+structure%22">Crystal structure</searchLink><br /><searchLink fieldCode="DE" term="%22Space+groups%22">Space groups</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+growth%22">Crystal growth</searchLink><br /><searchLink fieldCode="DE" term="%22Ethanol%22">Ethanol</searchLink>
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  Data: Crystals of the title compound BiCuI5(phen)2 were synthesized solvothermally by reacting CuCl2·2H2O, Bi(NO3)3·5H2O, NH4I, and 1,10-phenanthroline in an ethanol/water solvent mixture. BiCuI5(phen)2 crystallizes in the monoclinic space group P21/n. The asymmetric unit consists of a [Bi2I10] iodobismuthate group and a [CuI(phen)2] complex that are linked via a shared iodine. In this paper, we describe the synthesis and single crystal structure of the new metal–organic halobismuthate complex, BiCuI5(phen)2. X-ray diffraction quality single crystals of a novel metal–organic halobismuthate, BiCuI5(phen)2 were grown in water/ethanol solvent mixture at 120 °C and used for structure determination using single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of Chemical Crystallography is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1007/s10870-022-00932-6
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 394
    Subjects:
      – SubjectFull: Single crystals
        Type: general
      – SubjectFull: Crystal structure
        Type: general
      – SubjectFull: Space groups
        Type: general
      – SubjectFull: X-ray diffraction
        Type: general
      – SubjectFull: Crystal growth
        Type: general
      – SubjectFull: Ethanol
        Type: general
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      – TitleFull: Solvothermal Synthesis of BiCuI5(phen)2, a Novel Metal–Organic Halobismuthate.
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            NameFull: Morrison, Gregory
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            NameFull: Smith, Mark D.
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            NameFull: zur Loye, Hans-Conrad
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            – D: 01
              M: 09
              Text: Sep2022
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              Y: 2022
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