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A chemically functionalized glass support for gold and silver metallic nanoparticle analysis with LIBS.

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Title: A chemically functionalized glass support for gold and silver metallic nanoparticle analysis with LIBS.
Authors: Cárdenas-Escudero, J.1,2 (AUTHOR), Gardette, V.3 (AUTHOR), Villalonga, A.4 (AUTHOR), Sánchez, A.4 (AUTHOR), Villalonga, R.4 (AUTHOR) rvillalonga@quim.ucm.es, Motto-Ros, V.3 (AUTHOR) vincent.motto-ros@univ-lyon1.fr, Galán-Madruga, D.5 (AUTHOR) DAVID.GALAN@isciii.es, Cáceres, J. O.1 (AUTHOR) jcaceres@ucm.es
Source: JAAS (Journal of Analytical Atomic Spectrometry). Mar2024, Vol. 39 Issue 3, p962-973. 12p.
Subjects: Nanoparticles, Laser-induced breakdown spectroscopy, Silver, Gold, Gold nanoparticles, Sampling (Process), Raman scattering, Silver nanoparticles
Abstract: This work has focused on the development of a new analytical alternative based on the laser-induced breakdown spectroscopy (LIBS) technique for the fast, reliable, and economical determination of the gold and silver nanoparticle content in a low linear concentration range between 2.9 and 0.058 μg mL−1 and 2.9–0.116 μg mL−1, respectively, without requiring complicated sample pretreatment procedures or advanced separation techniques. Metallic nanoparticles are currently essential materials for the development of new technologies in different scientific and technical areas. However, numerous studies have pointed out these nanomaterials' toxic and polluting potential and the various health implications for humans, animals, and the ecosystem. The current reality reflects the lack of analytical techniques with low economic, environmental, and health impacts and the capacity to quantify the total metallic nanoparticle content. For this purpose, a novel and simple method for the selective capture of gold and silver nanoparticles, consisting of a chemically functionalized glass surface, has been custom-developed for subsequent analysis with LIBS. The results show that the proposed method, employing a functionalized sample glass support, presents a suitable analytical performance characterized by increased sensitivity, specifically 4.7% and 329.2% for Au-NPs and Ag-NPs, and proportionally decreased error in the slope and intercept of the calibration curves, 68% for Au-NPs and 87% for Ag-NPs, respectively. [ABSTRACT FROM AUTHOR]
Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 175992982
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PubTypeId: academicJournal
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  Data: A chemically functionalized glass support for gold and silver metallic nanoparticle analysis with LIBS.
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  Data: <searchLink fieldCode="AR" term="%22Cárdenas-Escudero%2C+J%2E%22">Cárdenas-Escudero, J.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gardette%2C+V%2E%22">Gardette, V.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Villalonga%2C+A%2E%22">Villalonga, A.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sánchez%2C+A%2E%22">Sánchez, A.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Villalonga%2C+R%2E%22">Villalonga, R.</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> rvillalonga@quim.ucm.es</i><br /><searchLink fieldCode="AR" term="%22Motto-Ros%2C+V%2E%22">Motto-Ros, V.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> vincent.motto-ros@univ-lyon1.fr</i><br /><searchLink fieldCode="AR" term="%22Galán-Madruga%2C+D%2E%22">Galán-Madruga, D.</searchLink><relatesTo>5</relatesTo> (AUTHOR)<i> DAVID.GALAN@isciii.es</i><br /><searchLink fieldCode="AR" term="%22Cáceres%2C+J%2E+O%2E%22">Cáceres, J. O.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> jcaceres@ucm.es</i>
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  Data: <searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Laser-induced+breakdown+spectroscopy%22">Laser-induced breakdown spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Silver%22">Silver</searchLink><br /><searchLink fieldCode="DE" term="%22Gold%22">Gold</searchLink><br /><searchLink fieldCode="DE" term="%22Gold+nanoparticles%22">Gold nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Sampling+%28Process%29%22">Sampling (Process)</searchLink><br /><searchLink fieldCode="DE" term="%22Raman+scattering%22">Raman scattering</searchLink><br /><searchLink fieldCode="DE" term="%22Silver+nanoparticles%22">Silver nanoparticles</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: This work has focused on the development of a new analytical alternative based on the laser-induced breakdown spectroscopy (LIBS) technique for the fast, reliable, and economical determination of the gold and silver nanoparticle content in a low linear concentration range between 2.9 and 0.058 μg mL−1 and 2.9–0.116 μg mL−1, respectively, without requiring complicated sample pretreatment procedures or advanced separation techniques. Metallic nanoparticles are currently essential materials for the development of new technologies in different scientific and technical areas. However, numerous studies have pointed out these nanomaterials' toxic and polluting potential and the various health implications for humans, animals, and the ecosystem. The current reality reflects the lack of analytical techniques with low economic, environmental, and health impacts and the capacity to quantify the total metallic nanoparticle content. For this purpose, a novel and simple method for the selective capture of gold and silver nanoparticles, consisting of a chemically functionalized glass surface, has been custom-developed for subsequent analysis with LIBS. The results show that the proposed method, employing a functionalized sample glass support, presents a suitable analytical performance characterized by increased sensitivity, specifically 4.7% and 329.2% for Au-NPs and Ag-NPs, and proportionally decreased error in the slope and intercept of the calibration curves, 68% for Au-NPs and 87% for Ag-NPs, respectively. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/d3ja00425b
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      – Code: eng
        Text: English
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        PageCount: 12
        StartPage: 962
    Subjects:
      – SubjectFull: Nanoparticles
        Type: general
      – SubjectFull: Laser-induced breakdown spectroscopy
        Type: general
      – SubjectFull: Silver
        Type: general
      – SubjectFull: Gold
        Type: general
      – SubjectFull: Gold nanoparticles
        Type: general
      – SubjectFull: Sampling (Process)
        Type: general
      – SubjectFull: Raman scattering
        Type: general
      – SubjectFull: Silver nanoparticles
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      – TitleFull: A chemically functionalized glass support for gold and silver metallic nanoparticle analysis with LIBS.
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              M: 03
              Text: Mar2024
              Type: published
              Y: 2024
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