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Correlation of homogenization effect with flotation separation between oxidized pyrite and dolomite.

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Title: Correlation of homogenization effect with flotation separation between oxidized pyrite and dolomite.
Authors: Zhao, Haiping1,2 (AUTHOR), Liu, Zhiwei2 (AUTHOR), Liu, Jingzhi2 (AUTHOR), Liang, Xinxing2 (AUTHOR), Hu, Xueping2 (AUTHOR), Duan, Wenquan2 (AUTHOR), Ma, Junsheng2 (AUTHOR), Gao, Liqiang2 (AUTHOR), Yu, Zifeng2 (AUTHOR), Ruan, Renman3,4 (AUTHOR)
Source: Minerals Engineering. Dec2024, Vol. 219, pN.PAG-N.PAG. 1p.
Subjects: Fourier transform infrared spectroscopy, Gold ores, X-ray photoelectron spectroscopy, Reflectance measurement, Ion exchange chromatography
Abstract: [Display omitted] • The interactions of pyrite and dolomite were proposed to clarify the low gold recovery of Carlin-type gold ores. • A stable and efficient oxidation method was performed to reveal the effects of oxidation degrees on the separation efficiency. • FTIR and XPS analysis were combined to correlate the surface specie transfer and xanthate adsorption with the change of floatability. • AFM, FBRM, PVM and E-DLVO calculations were conducted to demonstrate the adhesion between minerals and revealed the main driving force. This work attempts to clarify the reason for low gold recovery in Carlin-type gold ores flotation by revealing the correlation of interactions between pyrite and dolomite during the oxidation process with flotation performance. In this paper, the sulfur oxidation rate determined by Ion chromatography (IC) was adopted to evaluate the oxidation degrees of the mixed pyrite and dolomite systems. Flotation tests observed that the difference in the floating rate of pyrite and dolomite gradually decreases with the accumulation of oxidation degrees. The normalized Fourier Transform Infrared Spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) identified the homogenization effect that occurs between pyrite and dolomite surface during the oxidation process can change the affinity of the mineral surface towards the xanthate collector. Focused beam reflectance measurement (FBRM), Particle video microscope (PVM), and Extended Derjaguin–Landau–Verwey–Overbeek (E-DLVO) calculation show that the homogenization effect changes the interaction force between oxidized pyrite and dolomite, and caused the adhesion between minerals, ultimately, deteriorated the separation performance of Carlin-type gold deposits. This study can give a more detailed explanation of the reason for poor selectivity in the Carlin-type gold ores flotation. [ABSTRACT FROM AUTHOR]
Copyright of Minerals Engineering is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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  Data: Correlation of homogenization effect with flotation separation between oxidized pyrite and dolomite.
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  Data: <searchLink fieldCode="AR" term="%22Zhao%2C+Haiping%22">Zhao, Haiping</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Zhiwei%22">Liu, Zhiwei</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Jingzhi%22">Liu, Jingzhi</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liang%2C+Xinxing%22">Liang, Xinxing</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hu%2C+Xueping%22">Hu, Xueping</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Duan%2C+Wenquan%22">Duan, Wenquan</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ma%2C+Junsheng%22">Ma, Junsheng</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gao%2C+Liqiang%22">Gao, Liqiang</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yu%2C+Zifeng%22">Yu, Zifeng</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ruan%2C+Renman%22">Ruan, Renman</searchLink><relatesTo>3,4</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Minerals+Engineering%22">Minerals Engineering</searchLink>. Dec2024, Vol. 219, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Fourier+transform+infrared+spectroscopy%22">Fourier transform infrared spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Gold+ores%22">Gold ores</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+photoelectron+spectroscopy%22">X-ray photoelectron spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Reflectance+measurement%22">Reflectance measurement</searchLink><br /><searchLink fieldCode="DE" term="%22Ion+exchange+chromatography%22">Ion exchange chromatography</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: [Display omitted] • The interactions of pyrite and dolomite were proposed to clarify the low gold recovery of Carlin-type gold ores. • A stable and efficient oxidation method was performed to reveal the effects of oxidation degrees on the separation efficiency. • FTIR and XPS analysis were combined to correlate the surface specie transfer and xanthate adsorption with the change of floatability. • AFM, FBRM, PVM and E-DLVO calculations were conducted to demonstrate the adhesion between minerals and revealed the main driving force. This work attempts to clarify the reason for low gold recovery in Carlin-type gold ores flotation by revealing the correlation of interactions between pyrite and dolomite during the oxidation process with flotation performance. In this paper, the sulfur oxidation rate determined by Ion chromatography (IC) was adopted to evaluate the oxidation degrees of the mixed pyrite and dolomite systems. Flotation tests observed that the difference in the floating rate of pyrite and dolomite gradually decreases with the accumulation of oxidation degrees. The normalized Fourier Transform Infrared Spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) identified the homogenization effect that occurs between pyrite and dolomite surface during the oxidation process can change the affinity of the mineral surface towards the xanthate collector. Focused beam reflectance measurement (FBRM), Particle video microscope (PVM), and Extended Derjaguin–Landau–Verwey–Overbeek (E-DLVO) calculation show that the homogenization effect changes the interaction force between oxidized pyrite and dolomite, and caused the adhesion between minerals, ultimately, deteriorated the separation performance of Carlin-type gold deposits. This study can give a more detailed explanation of the reason for poor selectivity in the Carlin-type gold ores flotation. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Minerals Engineering is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.mineng.2024.109013
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Fourier transform infrared spectroscopy
        Type: general
      – SubjectFull: Gold ores
        Type: general
      – SubjectFull: X-ray photoelectron spectroscopy
        Type: general
      – SubjectFull: Reflectance measurement
        Type: general
      – SubjectFull: Ion exchange chromatography
        Type: general
    Titles:
      – TitleFull: Correlation of homogenization effect with flotation separation between oxidized pyrite and dolomite.
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            – D: 01
              M: 12
              Text: Dec2024
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              Y: 2024
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