View in EDS HTML Full Text PDF Full Text

Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Li, Liu, H. Wang, Fang, Jiang, Huang, Meng, and G. Wang

Saved in:
Bibliographic Details
Title: Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Li, Liu, H. Wang, Fang, Jiang, Huang, Meng, and G. Wang
Authors: Li, Wenwen1 (AUTHOR), Liu, Siqi1 (AUTHOR), Wang, Haomin1 (AUTHOR), Fang, Zhiqiang1 (AUTHOR), Jiang, Hao1 (AUTHOR), Huang, Ning1 (AUTHOR), Meng, Qingfei2 (AUTHOR), Wang, Guoqing1 (AUTHOR) wangguoqing@hainanu.edu.cn
Source: JOM: The Journal of The Minerals, Metals & Materials Society (TMS). May2025, Vol. 77 Issue 5, p3783-3792. 10p.
Subjects: Manufacturing processes, Chemical engineering, Tartaric acid, Organic acids, Industrial wastes
Abstract: Recycling waste lithium iron phosphate (LFP) batteries is crucial for reducing reliance on natural resources, minimizing environmental pollution. A selective leaching method for Li extraction from LiFePO4 is proposed using D-tartaric acid and H2O2. The investigation focused on evaluating the impact of various parameters including tartaric acid concentration, H2O2 dosage, solid–liquid (S–L) ratio, and reaction temperature and time on the leaching efficiencies (LE). Under optimal conditions, specifically, 1 M D-tartaric acid, 1 mL H2O2, an S–L ratio of 80 g/L, temperature of 75°C, and reaction time of 30 min, the LE of lithium reached 99.12%. The kinetic analysis of lithium leaching indicated that the process conformed most closely to the conforms to the Avrami model, with activation energies (Ea) calculated at 73.79 kJ/mol. To verify these findings, experiments were conducted on industrial waste LFP black powder, achieving a lithium leaching rate of over 99%. This study presents a clean and cost-effective method for lithium recovery by employing inexpensive and biodegradable organic acids. Furthermore, it offers a straightforward and efficient approach for processing industrial spent LFP black powder. [ABSTRACT FROM AUTHOR]
Copyright of JOM: The Journal of The Minerals, Metals & Materials Society (TMS) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Full text is not displayed to guests.
FullText Links:
  – Type: pdflink
Text:
  Availability: 1
Header DbId: egs
DbLabel: Engineering Source
An: 184490746
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Recovery of Lithium from Spent LiFePO<subscript>4</subscript> Cathodic Powders Through Tartaric Acid as a Leachant: Recovery of Lithium from Spent LiFePO<subscript>4</subscript> Cathodic Powders Through Tartaric Acid as a Leachant: Li, Liu, H. Wang, Fang, Jiang, Huang, Meng, and G. Wang
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Li%2C+Wenwen%22">Li, Wenwen</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Siqi%22">Liu, Siqi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Haomin%22">Wang, Haomin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Fang%2C+Zhiqiang%22">Fang, Zhiqiang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Hao%22">Jiang, Hao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Huang%2C+Ning%22">Huang, Ning</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Meng%2C+Qingfei%22">Meng, Qingfei</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Guoqing%22">Wang, Guoqing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wangguoqing@hainanu.edu.cn</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22JOM%3A+The+Journal+of+The+Minerals%2C+Metals+%26+Materials+Society+%28TMS%29%22">JOM: The Journal of The Minerals, Metals & Materials Society (TMS)</searchLink>. May2025, Vol. 77 Issue 5, p3783-3792. 10p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Manufacturing+processes%22">Manufacturing processes</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+engineering%22">Chemical engineering</searchLink><br /><searchLink fieldCode="DE" term="%22Tartaric+acid%22">Tartaric acid</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+acids%22">Organic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Industrial+wastes%22">Industrial wastes</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Recycling waste lithium iron phosphate (LFP) batteries is crucial for reducing reliance on natural resources, minimizing environmental pollution. A selective leaching method for Li extraction from LiFePO4 is proposed using D-tartaric acid and H2O2. The investigation focused on evaluating the impact of various parameters including tartaric acid concentration, H2O2 dosage, solid–liquid (S–L) ratio, and reaction temperature and time on the leaching efficiencies (LE). Under optimal conditions, specifically, 1 M D-tartaric acid, 1 mL H2O2, an S–L ratio of 80 g/L, temperature of 75°C, and reaction time of 30 min, the LE of lithium reached 99.12%. The kinetic analysis of lithium leaching indicated that the process conformed most closely to the conforms to the Avrami model, with activation energies (Ea) calculated at 73.79 kJ/mol. To verify these findings, experiments were conducted on industrial waste LFP black powder, achieving a lithium leaching rate of over 99%. This study presents a clean and cost-effective method for lithium recovery by employing inexpensive and biodegradable organic acids. Furthermore, it offers a straightforward and efficient approach for processing industrial spent LFP black powder. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of JOM: The Journal of The Minerals, Metals & Materials Society (TMS) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=184490746
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s11837-025-07281-7
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 10
        StartPage: 3783
    Subjects:
      – SubjectFull: Manufacturing processes
        Type: general
      – SubjectFull: Chemical engineering
        Type: general
      – SubjectFull: Tartaric acid
        Type: general
      – SubjectFull: Organic acids
        Type: general
      – SubjectFull: Industrial wastes
        Type: general
    Titles:
      – TitleFull: Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Recovery of Lithium from Spent LiFePO4 Cathodic Powders Through Tartaric Acid as a Leachant: Li, Liu, H. Wang, Fang, Jiang, Huang, Meng, and G. Wang
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Li, Wenwen
      – PersonEntity:
          Name:
            NameFull: Liu, Siqi
      – PersonEntity:
          Name:
            NameFull: Wang, Haomin
      – PersonEntity:
          Name:
            NameFull: Fang, Zhiqiang
      – PersonEntity:
          Name:
            NameFull: Jiang, Hao
      – PersonEntity:
          Name:
            NameFull: Huang, Ning
      – PersonEntity:
          Name:
            NameFull: Meng, Qingfei
      – PersonEntity:
          Name:
            NameFull: Wang, Guoqing
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 05
              Text: May2025
              Type: published
              Y: 2025
          Identifiers:
            – Type: issn-print
              Value: 10474838
          Numbering:
            – Type: volume
              Value: 77
            – Type: issue
              Value: 5
          Titles:
            – TitleFull: JOM: The Journal of The Minerals, Metals & Materials Society (TMS)
              Type: main
ResultId 1