Measurement and Modeling of the Solid–Liquid Equilibria in the Quinary System LiBr − NaBr − KBr − SrBr2 − H2O and Its Subsystems at 298.15 K.

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Title: Measurement and Modeling of the Solid–Liquid Equilibria in the Quinary System LiBr − NaBr − KBr − SrBr2 − H2O and Its Subsystems at 298.15 K.
Authors: Cui, Rui-Zhi1,2 (AUTHOR) cuirzh@isl.ac.cn, Nie, Guo-Liang1,2 (AUTHOR), Ren, Hong-Bao3 (AUTHOR), Yang, Qiu-Ye1,2 (AUTHOR), Li, Wu1,2 (AUTHOR)
Source: Journal of Solution Chemistry. Feb2026, Vol. 55 Issue 2, p290-305. 16p.
Subjects: Solid-liquid equilibrium, Phase diagrams, Mixtures, Inorganic compounds, Salt, Aqueous solutions, Sodium bromide, Potassium bromide
Abstract: Based on mother liquor rich in lithium, strontium and bromine obtained from the brine of underground oil–gas field in Qaidam Basin after pre-treatment, the isothermal dissolution equilibrium method was used to study the stable solid–liquid equilibria and phase diagrams of the quinary system LiBr − NaBr − KBr − SrBr2 − H2O and its subsystems at 298.15 K. The solubilities of solids in each system were determined, respectively, and the equilibrium solid phases were determined. In order to clearly reflect the regularities and characteristics of phase equilibria of multi-component systems, the corresponding phase diagrams were also plotted and analyzed. The Pitzer model for the quinary system was parameterized by using relevant experimental thermodynamic data. The solubilities of solids in this quinary system and its subsystems were calculated and compared with experimental results. The results not only help to reveal the thermodynamic behavior of relevant bromides in the process of brine concentration, but also provide some theoretical support for the comprehensive utilization of its brine resources. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Solution Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Measurement and Modeling of the Solid–Liquid Equilibria in the Quinary System LiBr − NaBr − KBr − SrBr<subscript>2</subscript> − H<subscript>2</subscript>O and Its Subsystems at 298.15 K.
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  Data: <searchLink fieldCode="AR" term="%22Cui%2C+Rui-Zhi%22">Cui, Rui-Zhi</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> cuirzh@isl.ac.cn</i><br /><searchLink fieldCode="AR" term="%22Nie%2C+Guo-Liang%22">Nie, Guo-Liang</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ren%2C+Hong-Bao%22">Ren, Hong-Bao</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Qiu-Ye%22">Yang, Qiu-Ye</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Wu%22">Li, Wu</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Solution+Chemistry%22">Journal of Solution Chemistry</searchLink>. Feb2026, Vol. 55 Issue 2, p290-305. 16p.
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  Data: <searchLink fieldCode="DE" term="%22Solid-liquid+equilibrium%22">Solid-liquid equilibrium</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+diagrams%22">Phase diagrams</searchLink><br /><searchLink fieldCode="DE" term="%22Mixtures%22">Mixtures</searchLink><br /><searchLink fieldCode="DE" term="%22Inorganic+compounds%22">Inorganic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Salt%22">Salt</searchLink><br /><searchLink fieldCode="DE" term="%22Aqueous+solutions%22">Aqueous solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Sodium+bromide%22">Sodium bromide</searchLink><br /><searchLink fieldCode="DE" term="%22Potassium+bromide%22">Potassium bromide</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Based on mother liquor rich in lithium, strontium and bromine obtained from the brine of underground oil–gas field in Qaidam Basin after pre-treatment, the isothermal dissolution equilibrium method was used to study the stable solid–liquid equilibria and phase diagrams of the quinary system LiBr − NaBr − KBr − SrBr2 − H2O and its subsystems at 298.15 K. The solubilities of solids in each system were determined, respectively, and the equilibrium solid phases were determined. In order to clearly reflect the regularities and characteristics of phase equilibria of multi-component systems, the corresponding phase diagrams were also plotted and analyzed. The Pitzer model for the quinary system was parameterized by using relevant experimental thermodynamic data. The solubilities of solids in this quinary system and its subsystems were calculated and compared with experimental results. The results not only help to reveal the thermodynamic behavior of relevant bromides in the process of brine concentration, but also provide some theoretical support for the comprehensive utilization of its brine resources. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Solution Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s10953-025-01513-9
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      – Code: eng
        Text: English
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        PageCount: 16
        StartPage: 290
    Subjects:
      – SubjectFull: Solid-liquid equilibrium
        Type: general
      – SubjectFull: Phase diagrams
        Type: general
      – SubjectFull: Mixtures
        Type: general
      – SubjectFull: Inorganic compounds
        Type: general
      – SubjectFull: Salt
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      – SubjectFull: Aqueous solutions
        Type: general
      – SubjectFull: Sodium bromide
        Type: general
      – SubjectFull: Potassium bromide
        Type: general
    Titles:
      – TitleFull: Measurement and Modeling of the Solid–Liquid Equilibria in the Quinary System LiBr − NaBr − KBr − SrBr2 − H2O and Its Subsystems at 298.15 K.
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            NameFull: Cui, Rui-Zhi
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            NameFull: Nie, Guo-Liang
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            NameFull: Ren, Hong-Bao
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            – D: 01
              M: 02
              Text: Feb2026
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              Y: 2026
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