Microstructure, mechanical, and tribological properties of Ti(C,N)-based cermets with in situ (Co,Ni)3Al.

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Title: Microstructure, mechanical, and tribological properties of Ti(C,N)-based cermets with in situ (Co,Ni)3Al.
Authors: Feng, Jiaying1,2 (AUTHOR), Liu, Qian1,2 (AUTHOR), Liu, Meiling1,2,3 (AUTHOR) meilingliu@nmu.edu.cn, Hai, Wanxiu1,2,3 (AUTHOR), Chen, Yuhong1,2 (AUTHOR)
Source: Journal of Materials Science. Jul2026, Vol. 61 Issue 27, p19551-19571. 21p.
Subjects: Aluminum nitride, Ceramic metals, Surface interactions, Grain refinement, Abrasion resistance, Sintering, Mechanical behavior of materials
Abstract: AlN@Ni powder, prepared by electroless plating, was used as an additive to fabricate Ti(C,N)-based cermets by vacuum pressureless sintering at 1600 °C. The introduction of AlN@Ni promoted solid-solution formation and in situ generation of (Co,Ni)3Al in the binder phase. The phase composition, microstructure, mechanical properties and tribological properties of the cermets were investigated. It was found that the addition of AlN@Ni significantly refined the grain size. When AlN@Ni content exceeded 3 wt%, (Co,Ni)3Al was in situ generated in the binder phase. The combined effects of fine grain strengthening and dispersion strengthening mechanisms led to optimal mechanical properties of the cermets with (Co,Ni)3Al. The Vickers' hardness, flexural strength and fracture toughness were 1608.1 MPa, 1565.8 MPa, and 9.3 MPa m1/2, respectively. The hardness and flexural strength increased by 21.4% and 40% compared to cermets without AlN@Ni. Moreover, the introduction of AlN@Ni and generation of (Co,Ni)3Al significantly improved the high-temperature wear resistance of the cermets, and the high-temperature volume wear rate was comparable to that at room temperature. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Microstructure, mechanical, and tribological properties of Ti(C,N)-based cermets with in situ (Co,Ni)<subscript>3</subscript>Al.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%22">Journal of Materials Science</searchLink>. Jul2026, Vol. 61 Issue 27, p19551-19571. 21p.
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  Data: <searchLink fieldCode="DE" term="%22Aluminum+nitride%22">Aluminum nitride</searchLink><br /><searchLink fieldCode="DE" term="%22Ceramic+metals%22">Ceramic metals</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+interactions%22">Surface interactions</searchLink><br /><searchLink fieldCode="DE" term="%22Grain+refinement%22">Grain refinement</searchLink><br /><searchLink fieldCode="DE" term="%22Abrasion+resistance%22">Abrasion resistance</searchLink><br /><searchLink fieldCode="DE" term="%22Sintering%22">Sintering</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: AlN@Ni powder, prepared by electroless plating, was used as an additive to fabricate Ti(C,N)-based cermets by vacuum pressureless sintering at 1600 °C. The introduction of AlN@Ni promoted solid-solution formation and in situ generation of (Co,Ni)3Al in the binder phase. The phase composition, microstructure, mechanical properties and tribological properties of the cermets were investigated. It was found that the addition of AlN@Ni significantly refined the grain size. When AlN@Ni content exceeded 3 wt%, (Co,Ni)3Al was in situ generated in the binder phase. The combined effects of fine grain strengthening and dispersion strengthening mechanisms led to optimal mechanical properties of the cermets with (Co,Ni)3Al. The Vickers' hardness, flexural strength and fracture toughness were 1608.1 MPa, 1565.8 MPa, and 9.3 MPa m1/2, respectively. The hardness and flexural strength increased by 21.4% and 40% compared to cermets without AlN@Ni. Moreover, the introduction of AlN@Ni and generation of (Co,Ni)3Al significantly improved the high-temperature wear resistance of the cermets, and the high-temperature volume wear rate was comparable to that at room temperature. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1007/s10853-026-13011-4
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      – Code: eng
        Text: English
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        PageCount: 21
        StartPage: 19551
    Subjects:
      – SubjectFull: Aluminum nitride
        Type: general
      – SubjectFull: Ceramic metals
        Type: general
      – SubjectFull: Surface interactions
        Type: general
      – SubjectFull: Grain refinement
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      – SubjectFull: Abrasion resistance
        Type: general
      – SubjectFull: Sintering
        Type: general
      – SubjectFull: Mechanical behavior of materials
        Type: general
    Titles:
      – TitleFull: Microstructure, mechanical, and tribological properties of Ti(C,N)-based cermets with in situ (Co,Ni)3Al.
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            NameFull: Feng, Jiaying
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            NameFull: Liu, Qian
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            NameFull: Liu, Meiling
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            NameFull: Hai, Wanxiu
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              Text: Jul2026
              Type: published
              Y: 2026
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