View in EDS

Self-assembly of two zinc complexes with flexible building block of 4-pyridylthioethylphosphonate

Saved in:
Bibliographic Details
Title: Self-assembly of two zinc complexes with flexible building block of 4-pyridylthioethylphosphonate
Authors: Guo, Li-Rong1, Bao, Song-Song1, Zheng, Li-Min lmzheng@nju.edu.cn
Source: Solid State Sciences. Feb2009, Vol. 11 Issue 2, p310-314. 5p.
Subjects: Molecular self-assembly, Metal complexes, Zinc compounds, Sulfides, Phosphonates, Ligands (Chemistry), Photoluminescence, X-ray crystallography
Abstract: Abstract: A new organophosphonate ligand containing sulfide group, 4-pyridylthioethylphosphonic acid hydrobromide (H2pytep·HBr), is synthesized through a facile route. Two zinc complexes of Zn2(pytepH2)2Br4 (1) and [Zn(pytep)]·H2O (2) are obtained by reacting H2pytep·HBr with zinc nitrate in solution and under hydrothermal condition, respectively. X-ray crystallographic studies reveal that 1 has a dinuclear structure in which the equivalent Zn atoms are doubly bridged by phosphonate groups. Compound 2 has a layer structure where ladder-like chains made up of corner-sharing {ZnNO3} and {CPO3} tetrahedra are linked by the organic groups of pytep. Photoluminescent properties are investigated. Different from complex 1 which shows no photoluminescence, complex 2 exhibits photoluminescence at 468nm (λ ex =353nm) in the solid state at room temperature. [Copyright &y& Elsevier]
Copyright of Solid State Sciences is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 36392491
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Self-assembly of two zinc complexes with flexible building block of 4-pyridylthioethylphosphonate
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Guo%2C+Li-Rong%22">Guo, Li-Rong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Bao%2C+Song-Song%22">Bao, Song-Song</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zheng%2C+Li-Min%22">Zheng, Li-Min</searchLink><i> lmzheng@nju.edu.cn</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Solid+State+Sciences%22">Solid State Sciences</searchLink>. Feb2009, Vol. 11 Issue 2, p310-314. 5p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Molecular+self-assembly%22">Molecular self-assembly</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Zinc+compounds%22">Zinc compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfides%22">Sulfides</searchLink><br /><searchLink fieldCode="DE" term="%22Phosphonates%22">Phosphonates</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Photoluminescence%22">Photoluminescence</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: A new organophosphonate ligand containing sulfide group, 4-pyridylthioethylphosphonic acid hydrobromide (H2pytep·HBr), is synthesized through a facile route. Two zinc complexes of Zn2(pytepH2)2Br4 (1) and [Zn(pytep)]·H2O (2) are obtained by reacting H2pytep·HBr with zinc nitrate in solution and under hydrothermal condition, respectively. X-ray crystallographic studies reveal that 1 has a dinuclear structure in which the equivalent Zn atoms are doubly bridged by phosphonate groups. Compound 2 has a layer structure where ladder-like chains made up of corner-sharing {ZnNO3} and {CPO3} tetrahedra are linked by the organic groups of pytep. Photoluminescent properties are investigated. Different from complex 1 which shows no photoluminescence, complex 2 exhibits photoluminescence at 468nm (λ ex =353nm) in the solid state at room temperature. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Solid State Sciences is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=36392491
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.solidstatesciences.2008.07.002
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 310
    Subjects:
      – SubjectFull: Molecular self-assembly
        Type: general
      – SubjectFull: Metal complexes
        Type: general
      – SubjectFull: Zinc compounds
        Type: general
      – SubjectFull: Sulfides
        Type: general
      – SubjectFull: Phosphonates
        Type: general
      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Photoluminescence
        Type: general
      – SubjectFull: X-ray crystallography
        Type: general
    Titles:
      – TitleFull: Self-assembly of two zinc complexes with flexible building block of 4-pyridylthioethylphosphonate
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Guo, Li-Rong
      – PersonEntity:
          Name:
            NameFull: Bao, Song-Song
      – PersonEntity:
          Name:
            NameFull: Zheng, Li-Min
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 02
              Text: Feb2009
              Type: published
              Y: 2009
          Identifiers:
            – Type: issn-print
              Value: 12932558
          Numbering:
            – Type: volume
              Value: 11
            – Type: issue
              Value: 2
          Titles:
            – TitleFull: Solid State Sciences
              Type: main
ResultId 1