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Ternary Sn–Sb–Co alloy film as new negative electrode for lithium-ion cells

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Title: Ternary Sn–Sb–Co alloy film as new negative electrode for lithium-ion cells
Authors: Tabuchi, T.1,2 toru.tabuchi@jp.gs-yuasa.com, Hochgatterer, N.1, Ogumi, Z.2, Winter, M.1
Source: Journal of Power Sources. Mar2009, Vol. 188 Issue 2, p552-557. 6p.
Subjects: Lithium-ion batteries, Electrodes, Metallic films, Tin alloys, Ternary alloys, Electroplating, Solution (Chemistry)
Abstract: Abstract: Ternary Sn–Sb–Co alloy film was successfully prepared by the co-electroplating method using an aqueous solution bath containing SnCl2·2H2O, CoCl2, SbCl3, Na2C4H4O6·2H2O, K3C6H5O7·H2O, and gelatine. The alloy composition was found to be mainly controllable by the amount of Na2C4H4O6·2H2O and SbCl3 in the plating bath. The Sn–Sb–Co film electrode with a composition of 75.4% Sn, 6.5% Sb, and 18.1% Co gave an initial discharge capacity of 380mAhg−1. The capacity gradually increased from the 1st to the 10th cycle and was then stabilized at a larger value of 580mAhg−1. Furthermore, the electrode was found to give better cycle performance compared to binary Sn–Co and Sn–Sb alloys. [Copyright &y& Elsevier]
Copyright of Journal of Power Sources is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 36769897
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Label: Title
  Group: Ti
  Data: Ternary Sn–Sb–Co alloy film as new negative electrode for lithium-ion cells
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  Data: <searchLink fieldCode="AR" term="%22Tabuchi%2C+T%2E%22">Tabuchi, T.</searchLink><relatesTo>1,2</relatesTo><i> toru.tabuchi@jp.gs-yuasa.com</i><br /><searchLink fieldCode="AR" term="%22Hochgatterer%2C+N%2E%22">Hochgatterer, N.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Ogumi%2C+Z%2E%22">Ogumi, Z.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Winter%2C+M%2E%22">Winter, M.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Power+Sources%22">Journal of Power Sources</searchLink>. Mar2009, Vol. 188 Issue 2, p552-557. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Lithium-ion+batteries%22">Lithium-ion batteries</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+films%22">Metallic films</searchLink><br /><searchLink fieldCode="DE" term="%22Tin+alloys%22">Tin alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Ternary+alloys%22">Ternary alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Electroplating%22">Electroplating</searchLink><br /><searchLink fieldCode="DE" term="%22Solution+%28Chemistry%29%22">Solution (Chemistry)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Ternary Sn–Sb–Co alloy film was successfully prepared by the co-electroplating method using an aqueous solution bath containing SnCl2·2H2O, CoCl2, SbCl3, Na2C4H4O6·2H2O, K3C6H5O7·H2O, and gelatine. The alloy composition was found to be mainly controllable by the amount of Na2C4H4O6·2H2O and SbCl3 in the plating bath. The Sn–Sb–Co film electrode with a composition of 75.4% Sn, 6.5% Sb, and 18.1% Co gave an initial discharge capacity of 380mAhg−1. The capacity gradually increased from the 1st to the 10th cycle and was then stabilized at a larger value of 580mAhg−1. Furthermore, the electrode was found to give better cycle performance compared to binary Sn–Co and Sn–Sb alloys. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Power Sources is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.jpowsour.2008.11.116
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      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 552
    Subjects:
      – SubjectFull: Lithium-ion batteries
        Type: general
      – SubjectFull: Electrodes
        Type: general
      – SubjectFull: Metallic films
        Type: general
      – SubjectFull: Tin alloys
        Type: general
      – SubjectFull: Ternary alloys
        Type: general
      – SubjectFull: Electroplating
        Type: general
      – SubjectFull: Solution (Chemistry)
        Type: general
    Titles:
      – TitleFull: Ternary Sn–Sb–Co alloy film as new negative electrode for lithium-ion cells
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            NameFull: Tabuchi, T.
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            NameFull: Hochgatterer, N.
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            NameFull: Ogumi, Z.
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            NameFull: Winter, M.
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            – D: 15
              M: 03
              Text: Mar2009
              Type: published
              Y: 2009
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            – TitleFull: Journal of Power Sources
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