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Geminal Atom Catalysts with Minimized d-Orbital Holes Enable β-Elimination-Resistant C(sp2)-C(sp3) Cross-Coupling.

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Title: Geminal Atom Catalysts with Minimized d-Orbital Holes Enable β-Elimination-Resistant C(sp2)-C(sp3) Cross-Coupling.
Authors: Wang Q; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China., Li T; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore., Huang P; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore., Yu Q; School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723001, P. R. China.; Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, P. R. China., Fu K; School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723001, P. R. China.; Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, P. R. China., Xi S; College of Design and Engineering, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute of Sustainability for Chemicals Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), Singapore 627833, Republic of Singapore.; Key Laboratory of Environmental Aquatic Chemistry, State Key Laboratory of Regional Environment and Sustainability Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P. R. China., Han X; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China., Hu J; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore., Zhao X; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China., Shao H; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore., Lin M; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore., Meng Y; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; National University of Singapore (Suzhou) Research Institute, No. 377 Linquan Street, Suzhou, Jiangsu 215123, P. R. China., Chen J; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore., Li J; Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China., Diao C; Singapore Synchrotron Light Source (SSLS), National University of Singapore, Singapore 117543, Republic of Singapore., Hai X; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China., Wang Y; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore., Fu X; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore., Sun J; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore., Novoselov KS; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore., Liu RY; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States., Li J; Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education, Tsinghua University, Beijing 100084, P. R. China.; Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China.; Fundamental Science Center of Rare Earths Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, P. R. China.; Guangdong Provincial Key Laboratory of Catalytic Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China., Lu J; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore.; National University of Singapore (Suzhou) Research Institute, No. 377 Linquan Street, Suzhou, Jiangsu 215123, P. R. China.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2026 Apr 22; Vol. 148 (15), pp. 16138-16150. Date of Electronic Publication: 2026 Apr 09.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE; PubMed not MEDLINE
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  Data: Geminal Atom Catalysts with Minimized d-Orbital Holes Enable β-Elimination-Resistant C(sp<superscript>2</superscript>)-C(sp<superscript>3</superscript>) Cross-Coupling.
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  Data: <searchLink fieldCode="AU" term="%22Wang+Q%22">Wang Q</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China.<br /><searchLink fieldCode="AU" term="%22Li+T%22">Li T</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Huang+P%22">Huang P</searchLink>; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Yu+Q%22">Yu Q</searchLink>; School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723001, P. R. China.; Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, P. R. China.<br /><searchLink fieldCode="AU" term="%22Fu+K%22">Fu K</searchLink>; School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723001, P. R. China.; Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, P. R. China.<br /><searchLink fieldCode="AU" term="%22Xi+S%22">Xi S</searchLink>; College of Design and Engineering, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute of Sustainability for Chemicals Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), Singapore 627833, Republic of Singapore.; Key Laboratory of Environmental Aquatic Chemistry, State Key Laboratory of Regional Environment and Sustainability Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, P. R. China.<br /><searchLink fieldCode="AU" term="%22Han+X%22">Han X</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China.<br /><searchLink fieldCode="AU" term="%22Hu+J%22">Hu J</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Zhao+X%22">Zhao X</searchLink>; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China.<br /><searchLink fieldCode="AU" term="%22Shao+H%22">Shao H</searchLink>; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Lin+M%22">Lin M</searchLink>; Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Meng+Y%22">Meng Y</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; National University of Singapore (Suzhou) Research Institute, No. 377 Linquan Street, Suzhou, Jiangsu 215123, P. R. China.<br /><searchLink fieldCode="AU" term="%22Chen+J%22">Chen J</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Li+J%22">Li J</searchLink>; Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China.<br /><searchLink fieldCode="AU" term="%22Diao+C%22">Diao C</searchLink>; Singapore Synchrotron Light Source (SSLS), National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Hai+X%22">Hai X</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China.<br /><searchLink fieldCode="AU" term="%22Wang+Y%22">Wang Y</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Fu+X%22">Fu X</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Sun+J%22">Sun J</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Novoselov+KS%22">Novoselov KS</searchLink>; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore.<br /><searchLink fieldCode="AU" term="%22Liu+RY%22">Liu RY</searchLink>; Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.<br /><searchLink fieldCode="AU" term="%22Li+J%22">Li J</searchLink>; Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education, Tsinghua University, Beijing 100084, P. R. China.; Department of Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China.; Fundamental Science Center of Rare Earths Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, P. R. China.; Guangdong Provincial Key Laboratory of Catalytic Chemistry, Southern University of Science and Technology, Shenzhen 518055, P. R. China.<br /><searchLink fieldCode="AU" term="%22Lu+J%22">Lu J</searchLink>; Department of Chemistry, National University of Singapore, Singapore 117543, Republic of Singapore.; Institute for Functional Intelligent Materials, National University of Singapore, Singapore 117543, Republic of Singapore.; National University of Singapore (Suzhou) Research Institute, No. 377 Linquan Street, Suzhou, Jiangsu 215123, P. R. China.
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  Data: <searchLink fieldCode="JN" term="%227503056%22">Journal of the American Chemical Society</searchLink> [J Am Chem Soc] 2026 Apr 22; Vol. 148 (15), pp. 16138-16150. <i>Date of Electronic Publication: </i>2026 Apr 09.
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