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Cobalt-Catalyzed Asymmetric Cyclopropanation of Heteroaryl Alkenes with Homogeneous Zinc Carbenoids.

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Title: Cobalt-Catalyzed Asymmetric Cyclopropanation of Heteroaryl Alkenes with Homogeneous Zinc Carbenoids.
Authors: Deem MC; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Lehnherr D; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Wang T; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Wang X; Analytical Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Lam YH; Computational and Structural Chemistry, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Silverman SM; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Newman JA; Analytical Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Lin Q; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Phillips EM; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Christensen M; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Chung CK; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Zhou Z; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States., Yang H; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.
Source: Journal of the American Chemical Society [J Am Chem Soc] 2026 May 27; Vol. 148 (20), pp. 21029-21042. Date of Electronic Publication: 2026 May 14.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: MEDLINE; PubMed not MEDLINE
Database: MEDLINE Ultimate
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  Data: Cobalt-Catalyzed Asymmetric Cyclopropanation of Heteroaryl Alkenes with Homogeneous Zinc Carbenoids.
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  Data: <searchLink fieldCode="AU" term="%22Deem+MC%22">Deem MC</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Lehnherr+D%22">Lehnherr D</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Wang+T%22">Wang T</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Wang+X%22">Wang X</searchLink>; Analytical Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Lam+YH%22">Lam YH</searchLink>; Computational and Structural Chemistry, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Silverman+SM%22">Silverman SM</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Newman+JA%22">Newman JA</searchLink>; Analytical Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Lin+Q%22">Lin Q</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Phillips+EM%22">Phillips EM</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Christensen+M%22">Christensen M</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Chung+CK%22">Chung CK</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Zhou+Z%22">Zhou Z</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.<br /><searchLink fieldCode="AU" term="%22Yang+H%22">Yang H</searchLink>; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, United States.
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  Data: <searchLink fieldCode="JN" term="%227503056%22">Journal of the American Chemical Society</searchLink> [J Am Chem Soc] 2026 May 27; Vol. 148 (20), pp. 21029-21042. <i>Date of Electronic Publication: </i>2026 May 14.
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