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The propensity for covalent organic frameworks to template polymer entanglement.

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Title: The propensity for covalent organic frameworks to template polymer entanglement.
Authors: Neumann, S. Ephraim, Kwon, Junpyo, Gropp, Cornelius, Le Ma, Giovine, Raynald, Tianqiong Ma, Hanikel, Nikita, Kaiyu Wang, Chen, Tiffany, Shaan Jagani, Ritchie, Robert O., Ting Xu, Yaghi, Omar M.
Source: Science (pre-March 2025). 3/22/2024, Vol. 383 Issue 6689, p1337-1343. 7p. 4 Diagrams.
Subjects: Crystalline polymers, Spatial arrangement, Surface interactions, Three-dimensional textiles, Polymers
Abstract: The introduction of molecularly woven three-dimensional (3D) covalent organic framework (COF) crystals into polymers of varying types invokes different forms of contact between filler and polymer. Whereas the combination of woven COFs with amorphous and brittle polymethyl methacrylate results in surface interactions, the use of the liquid-crystalline polymer polyimide induces the formation of polymer-COF junctions. These junctions are generated by the threading of polymer chains through the pores of the nanocrystals, thus allowing for spatial arrangement of polymer strands. This offers a programmable pathway for unthreading polymer strands under stress and leads to the in situ formation of high-aspect-ratio nanofibrils, which dissipate energy during the fracture. Polymer-COF junctions also strengthen the filler-matrix interfaces and lower the percolation thresholds of the composites, enhancing strength, ductility, and toughness of the composites by adding small amounts (~1 weight %) of woven COF nanocrystals. The ability of the polymer strands to closely interact with the woven framework is highlighted as the main parameter to forming these junctions, thus affecting polymer chain penetration and conformation. [ABSTRACT FROM AUTHOR]
Copyright of Science (pre-March 2025) is the property of American Association for the Advancement of Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Psychology and Behavioral Sciences Collection
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  Data: The propensity for covalent organic frameworks to template polymer entanglement.
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  Data: <searchLink fieldCode="AR" term="%22Neumann%2C+S%2E+Ephraim%22">Neumann, S. Ephraim</searchLink><br /><searchLink fieldCode="AR" term="%22Kwon%2C+Junpyo%22">Kwon, Junpyo</searchLink><br /><searchLink fieldCode="AR" term="%22Gropp%2C+Cornelius%22">Gropp, Cornelius</searchLink><br /><searchLink fieldCode="AR" term="%22Le+Ma%22">Le Ma</searchLink><br /><searchLink fieldCode="AR" term="%22Giovine%2C+Raynald%22">Giovine, Raynald</searchLink><br /><searchLink fieldCode="AR" term="%22Tianqiong+Ma%22">Tianqiong Ma</searchLink><br /><searchLink fieldCode="AR" term="%22Hanikel%2C+Nikita%22">Hanikel, Nikita</searchLink><br /><searchLink fieldCode="AR" term="%22Kaiyu+Wang%22">Kaiyu Wang</searchLink><br /><searchLink fieldCode="AR" term="%22Chen%2C+Tiffany%22">Chen, Tiffany</searchLink><br /><searchLink fieldCode="AR" term="%22Shaan+Jagani%22">Shaan Jagani</searchLink><br /><searchLink fieldCode="AR" term="%22Ritchie%2C+Robert+O%2E%22">Ritchie, Robert O.</searchLink><br /><searchLink fieldCode="AR" term="%22Ting+Xu%22">Ting Xu</searchLink><br /><searchLink fieldCode="AR" term="%22Yaghi%2C+Omar+M%2E%22">Yaghi, Omar M.</searchLink>
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  Data: <searchLink fieldCode="JN" term="%22Science+%28pre-March+2025%29%22">Science (pre-March 2025)</searchLink>. 3/22/2024, Vol. 383 Issue 6689, p1337-1343. 7p. 4 Diagrams.
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  Data: <searchLink fieldCode="DE" term="%22Crystalline+polymers%22">Crystalline polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Spatial+arrangement%22">Spatial arrangement</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+interactions%22">Surface interactions</searchLink><br /><searchLink fieldCode="DE" term="%22Three-dimensional+textiles%22">Three-dimensional textiles</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink>
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  Data: The introduction of molecularly woven three-dimensional (3D) covalent organic framework (COF) crystals into polymers of varying types invokes different forms of contact between filler and polymer. Whereas the combination of woven COFs with amorphous and brittle polymethyl methacrylate results in surface interactions, the use of the liquid-crystalline polymer polyimide induces the formation of polymer-COF junctions. These junctions are generated by the threading of polymer chains through the pores of the nanocrystals, thus allowing for spatial arrangement of polymer strands. This offers a programmable pathway for unthreading polymer strands under stress and leads to the in situ formation of high-aspect-ratio nanofibrils, which dissipate energy during the fracture. Polymer-COF junctions also strengthen the filler-matrix interfaces and lower the percolation thresholds of the composites, enhancing strength, ductility, and toughness of the composites by adding small amounts (~1 weight %) of woven COF nanocrystals. The ability of the polymer strands to closely interact with the woven framework is highlighted as the main parameter to forming these junctions, thus affecting polymer chain penetration and conformation. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Science (pre-March 2025) is the property of American Association for the Advancement of Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1126/science.adf2573
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        Text: English
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        PageCount: 7
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      – SubjectFull: Crystalline polymers
        Type: general
      – SubjectFull: Spatial arrangement
        Type: general
      – SubjectFull: Surface interactions
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      – SubjectFull: Polymers
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      – TitleFull: The propensity for covalent organic frameworks to template polymer entanglement.
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              M: 03
              Text: 3/22/2024
              Type: published
              Y: 2024
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