The potential utility of dendritic fibrous nanosilica as an adsorbent and a catalyst in carbon capture, utilization, and storage.

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Title: The potential utility of dendritic fibrous nanosilica as an adsorbent and a catalyst in carbon capture, utilization, and storage.
Authors: Lim, Sam Yeol1 (AUTHOR), Younis, Sherif A.2 (AUTHOR), Kim, Ki-Hyun3 (AUTHOR) kkim61@hanyang.ac.kr, Lee, Jechan4 (AUTHOR) jechanlee@skku.edu
Source: Chemical Society Reviews. 10/21/2024, Vol. 53 Issue 20, p9976-10011. 36p.
Subjects: Greenhouse gases, Carbon sequestration, Climate change, Porosity, Carbon monoxide
Abstract: Anthropogenic emissions of greenhouse gases (GHG; e.g., CO2) are regarded as the most critical cause of the current global climate crisis. To combat this issue, a plethora of CO2 capture, utilization, and storage (CCUS) technologies have been proposed and developed based on a number of technical principles (e.g., post-combustion capture, chemical looping, and catalytic conversion). In this light, the potential utility of dendritic fibrous nanosilica (DFNS) materials is recognized for specific CCUS applications (such as adsorptive capture of CO2 and its catalytic conversion into a list of value-added products (e.g., methane, carbon monoxide, and cyclic carbonates)) with the highly tunable properties (e.g., high surface area, pore volume, multifunctional surface, and open pore structure). This review has been organized to offer a comprehensive evaluation of the approaches required for tuning the textural/morphological/surface properties of DFNS (based on multiple synthesis and modification scenarios) toward CCUS applications. It further discusses the effects of such approaches on the properties of DFNS materials in relation to their CCUS performance. This review is thus expected to help develop and implement advanced strategies for DFNS-based CCUS technologies. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:Anthropogenic emissions of greenhouse gases (GHG; e.g., CO2) are regarded as the most critical cause of the current global climate crisis. To combat this issue, a plethora of CO2 capture, utilization, and storage (CCUS) technologies have been proposed and developed based on a number of technical principles (e.g., post-combustion capture, chemical looping, and catalytic conversion). In this light, the potential utility of dendritic fibrous nanosilica (DFNS) materials is recognized for specific CCUS applications (such as adsorptive capture of CO2 and its catalytic conversion into a list of value-added products (e.g., methane, carbon monoxide, and cyclic carbonates)) with the highly tunable properties (e.g., high surface area, pore volume, multifunctional surface, and open pore structure). This review has been organized to offer a comprehensive evaluation of the approaches required for tuning the textural/morphological/surface properties of DFNS (based on multiple synthesis and modification scenarios) toward CCUS applications. It further discusses the effects of such approaches on the properties of DFNS materials in relation to their CCUS performance. This review is thus expected to help develop and implement advanced strategies for DFNS-based CCUS technologies. [ABSTRACT FROM AUTHOR]
ISSN:03060012
DOI:10.1039/d4cs00564c