Kinetic theory of diffusion in a channel of varying cross section.

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Title: Kinetic theory of diffusion in a channel of varying cross section.
Authors: Brey, J. Javier1,2 (AUTHOR) brey@us.es, García de Soria, M. I.1 (AUTHOR), Maynar, P.1 (AUTHOR)
Source: Molecular Physics. Nov2024, Vol. 122 Issue 21/22, p1-12. 12p.
Subjects: Transport equation, Evolution equations, Diffusion coefficients, Transversal lines, Equilibrium
Abstract: Self-diffusion along the longitudinal coordinate in a channel of varying cross section is considered. The starting point is the two-dimensional Enskog-Boltzmann-Lorentz kinetic equation with appropriated boundary conditions. It is integrated over the transversal coordinate to get an approximated one-dimensional kinetic equation, keeping the relevant properties of the original one. Then, a macroscopic equation for the time evolution of the longitudinal density is derived, by means of a modified Chapman-Enskog expansion method, that takes into account the inhomogeneity of the equilibrium longitudinal density. This transport equation has the form of the phenomenological Ficks-Jacobs equation, but with an effective diffusion coefficient that contains corrections associated to the variation of the slope of the equilibrium longitudinal density profile. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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Abstract:Self-diffusion along the longitudinal coordinate in a channel of varying cross section is considered. The starting point is the two-dimensional Enskog-Boltzmann-Lorentz kinetic equation with appropriated boundary conditions. It is integrated over the transversal coordinate to get an approximated one-dimensional kinetic equation, keeping the relevant properties of the original one. Then, a macroscopic equation for the time evolution of the longitudinal density is derived, by means of a modified Chapman-Enskog expansion method, that takes into account the inhomogeneity of the equilibrium longitudinal density. This transport equation has the form of the phenomenological Ficks-Jacobs equation, but with an effective diffusion coefficient that contains corrections associated to the variation of the slope of the equilibrium longitudinal density profile. [ABSTRACT FROM AUTHOR]
ISSN:00268976
DOI:10.1080/00268976.2024.2378116