Mechanical and thermal characterization of epoxy/polysulfide polymer blend-based nanocomposites filled with alumina trihydrate nanoparticles.

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Title: Mechanical and thermal characterization of epoxy/polysulfide polymer blend-based nanocomposites filled with alumina trihydrate nanoparticles.
Authors: Abdulla, Aso O.1 (AUTHOR), Jamal, Gelas M.2 (AUTHOR), Rostam, Sarkawt3 (AUTHOR) sarkawt.rostam@spu.edu.iq
Source: Polymers & Polymer Composites. 2/28/2026, Vol. 34, p1-21. 21p.
Subjects: Nanocomposite materials, Polymer blends, Scanning electron microscopy, Polysulfides, Thermal properties, Nanoparticles, X-ray diffraction, Mechanical behavior of materials
Abstract: This research aims to characterize the mechanical and thermal properties of a blend of epoxy (EPR) and polysulfide (PS) that incorporates alumina trihydrate (ATH) nanoparticles (NPs). The purpose is to investigate the effect of adding NPs on the properties of the resulting epoxy-polymer blends. The polymer blend nanocomposites (PBNCs) were prepared from EPR and PS by adding different concentrations (1 wt.%, 3 wt.%, and 5 wt.%) of ATH NPs. The hand lay-up molding method was utilized to prepare the samples. The mechanical and thermal characteristics of the specimens have been studied. The structure and formation of the blend (EPR/PS) and the dispersion of NPs inside the blend and epoxy were confirmed by X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). Mechanical behaviour through tensile, flexural, and hardness tests was carried out on polymer blends and composites. The results show that the maximum toughness for PBNCs and EPR NCs was recorded at 5 wt% ATH NPs, exhibiting enhancements of 54.22% and 206.5% above pure EPR, respectively. Maximum elongation at break is observed at 5 wt.% of ATH nanoparticles, with increases of 312.45% and 425.36% for PBNC and EPR nanocomposites, respectively, in comparison to EPR. The maximum hardness is 86.26 at 5 wt.% of ATH nanoparticles for EPR nanocomposites. While the maximum flexural strength (75.05 MPa) and flexural modulus (2406.69 MPa) for EPR NCs exhibited increases of 20.62% and 37%, respectively, in comparison to EPR (1756.73 MPa). The XRD pattern showed a favourable interaction among the components in the EPR/PS blend and the NCs. SEM micrographs revealed that the blend has a single face, and the NPs were effectively dispersed into the prepared composites. The examination of thermogravimetric analysis-derivative thermogravimetry (TGA-DTG) data indicates that the enhanced thermal stability of EPRNCs and PBNCs contrasts with that of the EPR/PS blend. [ABSTRACT FROM AUTHOR]
Copyright of Polymers & Polymer Composites is the property of Sage Publications Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Mechanical and thermal characterization of epoxy/polysulfide polymer blend-based nanocomposites filled with alumina trihydrate nanoparticles.
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  Data: <searchLink fieldCode="AR" term="%22Abdulla%2C+Aso+O%2E%22">Abdulla, Aso O.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jamal%2C+Gelas+M%2E%22">Jamal, Gelas M.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Rostam%2C+Sarkawt%22">Rostam, Sarkawt</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> sarkawt.rostam@spu.edu.iq</i>
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%26+Polymer+Composites%22">Polymers & Polymer Composites</searchLink>. 2/28/2026, Vol. 34, p1-21. 21p.
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  Data: <searchLink fieldCode="DE" term="%22Nanocomposite+materials%22">Nanocomposite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Polymer+blends%22">Polymer blends</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopy%22">Scanning electron microscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Polysulfides%22">Polysulfides</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+properties%22">Thermal properties</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: This research aims to characterize the mechanical and thermal properties of a blend of epoxy (EPR) and polysulfide (PS) that incorporates alumina trihydrate (ATH) nanoparticles (NPs). The purpose is to investigate the effect of adding NPs on the properties of the resulting epoxy-polymer blends. The polymer blend nanocomposites (PBNCs) were prepared from EPR and PS by adding different concentrations (1 wt.%, 3 wt.%, and 5 wt.%) of ATH NPs. The hand lay-up molding method was utilized to prepare the samples. The mechanical and thermal characteristics of the specimens have been studied. The structure and formation of the blend (EPR/PS) and the dispersion of NPs inside the blend and epoxy were confirmed by X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). Mechanical behaviour through tensile, flexural, and hardness tests was carried out on polymer blends and composites. The results show that the maximum toughness for PBNCs and EPR NCs was recorded at 5 wt% ATH NPs, exhibiting enhancements of 54.22% and 206.5% above pure EPR, respectively. Maximum elongation at break is observed at 5 wt.% of ATH nanoparticles, with increases of 312.45% and 425.36% for PBNC and EPR nanocomposites, respectively, in comparison to EPR. The maximum hardness is 86.26 at 5 wt.% of ATH nanoparticles for EPR nanocomposites. While the maximum flexural strength (75.05 MPa) and flexural modulus (2406.69 MPa) for EPR NCs exhibited increases of 20.62% and 37%, respectively, in comparison to EPR (1756.73 MPa). The XRD pattern showed a favourable interaction among the components in the EPR/PS blend and the NCs. SEM micrographs revealed that the blend has a single face, and the NPs were effectively dispersed into the prepared composites. The examination of thermogravimetric analysis-derivative thermogravimetry (TGA-DTG) data indicates that the enhanced thermal stability of EPRNCs and PBNCs contrasts with that of the EPR/PS blend. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Polymers & Polymer Composites is the property of Sage Publications Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1177/09673911261429553
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      – Code: eng
        Text: English
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        PageCount: 21
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    Subjects:
      – SubjectFull: Nanocomposite materials
        Type: general
      – SubjectFull: Polymer blends
        Type: general
      – SubjectFull: Scanning electron microscopy
        Type: general
      – SubjectFull: Polysulfides
        Type: general
      – SubjectFull: Thermal properties
        Type: general
      – SubjectFull: Nanoparticles
        Type: general
      – SubjectFull: X-ray diffraction
        Type: general
      – SubjectFull: Mechanical behavior of materials
        Type: general
    Titles:
      – TitleFull: Mechanical and thermal characterization of epoxy/polysulfide polymer blend-based nanocomposites filled with alumina trihydrate nanoparticles.
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            NameFull: Abdulla, Aso O.
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            NameFull: Jamal, Gelas M.
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            NameFull: Rostam, Sarkawt
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            – D: 28
              M: 02
              Text: 2/28/2026
              Type: published
              Y: 2026
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              Value: 34
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