Effect of pore-forming agents on the microstructures and properties of diatomite-based porous ceramics.

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Title: Effect of pore-forming agents on the microstructures and properties of diatomite-based porous ceramics.
Authors: Jiao, Fan1 (AUTHOR), Fang, Cheng1 (AUTHOR), Xu, Hongliang1,2 (AUTHOR) xhlxhl@zzu.edu.cn, Song, Bo1 (AUTHOR), Wang, Ruiyang1 (AUTHOR), Li, Mingliang1,2 (AUTHOR), Wang, Hailiang1,2 (AUTHOR), Shao, Gang1 (AUTHOR), Lu, Hongxia1,2 (AUTHOR), Wang, Hailong1,2 (AUTHOR)
Source: Ceramics International. Jun2026:Part A, Vol. 52 Issue 14, p24817-24825. 9p.
Subjects: Porous materials, Wastewater treatment, Permeability, Sintering, Microstructure, Mechanical behavior of materials, Graphite, Porosity
Abstract: Diatomite-based porous ceramics were prepared using single or composite pore-forming agents, with the aiding of pressureless sintering method and sintering aids. The microstructure, mechanical property and permeation flux of the ceramics varied with pore-forming agent types and the mass ratio of spherical graphite and flake graphite in the composite pore-forming agent. Among all the single pore-forming agents, spherical graphite and flake graphite achieved the highest flexural strength and permeation flux, respectively. With the mass ratio of 3:1, the diatomite porous ceramics obtained the optimum comprehensive properties with bead-like-micro-nano hierarchical pore structures, achieving high flexural strength (13.8 MPa), high porosity (∼60%) with a pore size range mainly in 0.5-34 μm, and high permeation flux of 887.82 L m−2 h−1·bar−1. The porous ceramic could efficiently intercept the alumina particles larger than 144.5 nm and separate the oil-water mixtures. This study offers a viable pathway for developing high-performance diatomite-based porous ceramics tailored for advanced wastewater treatment techniques. [Display omitted] • Diatomite porous ceramics obtained high flexural strength and permeation flux. • Single and composite pore-forming agents were introduced to ceramic bodies. • Spherical and flake graphite jointly create internal bead-like micropore structures. • Nanopores of diatomite and micropores construct hierarchical pore architectures. • Diatomite porous ceramics exhibited great filtrate and separation performance. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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Abstract:Diatomite-based porous ceramics were prepared using single or composite pore-forming agents, with the aiding of pressureless sintering method and sintering aids. The microstructure, mechanical property and permeation flux of the ceramics varied with pore-forming agent types and the mass ratio of spherical graphite and flake graphite in the composite pore-forming agent. Among all the single pore-forming agents, spherical graphite and flake graphite achieved the highest flexural strength and permeation flux, respectively. With the mass ratio of 3:1, the diatomite porous ceramics obtained the optimum comprehensive properties with bead-like-micro-nano hierarchical pore structures, achieving high flexural strength (13.8 MPa), high porosity (∼60%) with a pore size range mainly in 0.5-34 μm, and high permeation flux of 887.82 L m−2 h−1·bar−1. The porous ceramic could efficiently intercept the alumina particles larger than 144.5 nm and separate the oil-water mixtures. This study offers a viable pathway for developing high-performance diatomite-based porous ceramics tailored for advanced wastewater treatment techniques. [Display omitted] • Diatomite porous ceramics obtained high flexural strength and permeation flux. • Single and composite pore-forming agents were introduced to ceramic bodies. • Spherical and flake graphite jointly create internal bead-like micropore structures. • Nanopores of diatomite and micropores construct hierarchical pore architectures. • Diatomite porous ceramics exhibited great filtrate and separation performance. [ABSTRACT FROM AUTHOR]
ISSN:02728842
DOI:10.1016/j.ceramint.2026.04.046