Recent developments in the chemistry of organic perfluoro hypofluorites.
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| Title: | Recent developments in the chemistry of organic perfluoro hypofluorites. |
|---|---|
| Authors: | Francesco, Venturini1,2, Sansotera, Maurizio1,2, Navarrini, Walter1,2 walter.navarrini@polimi.it |
| Source: | Journal of Fluorine Chemistry. Nov2013, Vol. 155, p2-20. 19p. |
| Subjects: | Hypofluorites, Perfluoro compounds, Organic chemistry, Monomers, Intermediates (Chemistry), Electrophiles |
| Abstract: | Highlights: [•] Hypofluorites are key intermediates in the synthesis of fluoromonomers. [•] The reaction of hypofluorites with double bond is fundamental. [•] The hypofluorites having formula RFOCF2OF are stable. [•] The electrophilic character of the CF3O radical was proven. [•] The ratio CF3OCFClCF2Cl/CF3OCFClC(O)F is a competitive reaction evaluation. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Fluorine Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 90214397 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Recent developments in the chemistry of organic perfluoro hypofluorites. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Francesco%2C+Venturini%22">Francesco, Venturini</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Sansotera%2C+Maurizio%22">Sansotera, Maurizio</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Navarrini%2C+Walter%22">Navarrini, Walter</searchLink><relatesTo>1,2</relatesTo><i> walter.navarrini@polimi.it</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Fluorine+Chemistry%22">Journal of Fluorine Chemistry</searchLink>. Nov2013, Vol. 155, p2-20. 19p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Hypofluorites%22">Hypofluorites</searchLink><br /><searchLink fieldCode="DE" term="%22Perfluoro+compounds%22">Perfluoro compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+chemistry%22">Organic chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Monomers%22">Monomers</searchLink><br /><searchLink fieldCode="DE" term="%22Intermediates+%28Chemistry%29%22">Intermediates (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Electrophiles%22">Electrophiles</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Highlights: [•] Hypofluorites are key intermediates in the synthesis of fluoromonomers. [•] The reaction of hypofluorites with double bond is fundamental. [•] The hypofluorites having formula RFOCF2OF are stable. [•] The electrophilic character of the CF3O radical was proven. [•] The ratio CF3OCFClCF2Cl/CF3OCFClC(O)F is a competitive reaction evaluation. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Fluorine Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.jfluchem.2013.07.005 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 19 StartPage: 2 Subjects: – SubjectFull: Hypofluorites Type: general – SubjectFull: Perfluoro compounds Type: general – SubjectFull: Organic chemistry Type: general – SubjectFull: Monomers Type: general – SubjectFull: Intermediates (Chemistry) Type: general – SubjectFull: Electrophiles Type: general Titles: – TitleFull: Recent developments in the chemistry of organic perfluoro hypofluorites. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Francesco, Venturini – PersonEntity: Name: NameFull: Sansotera, Maurizio – PersonEntity: Name: NameFull: Navarrini, Walter IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 11 Text: Nov2013 Type: published Y: 2013 Identifiers: – Type: issn-print Value: 00221139 Numbering: – Type: volume Value: 155 Titles: – TitleFull: Journal of Fluorine Chemistry Type: main |
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