Discrete modelling of ion diffusion in clays with overlapped electrical double layers.
Saved in:
| Title: | Discrete modelling of ion diffusion in clays with overlapped electrical double layers. |
|---|---|
| Authors: | Qu, Yongxiao1 (AUTHOR), Li, Bo1 (AUTHOR), Wang, LiGe2 (AUTHOR), Yan, Huaxiang3 (AUTHOR), Bian, Kang4 (AUTHOR), Jivkov, Andrey P.5 (AUTHOR), Xiong, Qingrong1 (AUTHOR) qingrong.xiong@sdu.edu.cn |
| Source: | Journal of Radioanalytical & Nuclear Chemistry. May2026, Vol. 335 Issue 5, p3937-3951. 15p. |
| Subject Terms: | *Electric double layer, *Debye length, *Ion migration & velocity, *Ion mobility, *Clay, *Van der Waals forces, *Porosity, *Computer simulation |
| Abstract: | The electrical double layer (EDL) critically influences ion transport prediction in clay, yet current models fail to accurately simulate diffusion in highly compacted clay across broad ionic strengths, especially low concentrations (e.g., 0.01 mol/L). This work proposes a robust model integrating a pore network approach with pore-specific ion transport. Pores are categorized into three types based on Debye length and EDL overlap degree. Van der Waals forces are incorporated for pores with severe EDL overlap. The numerical results predicted under a larger span of anion and cation concentration agree well with the experimental data. [ABSTRACT FROM AUTHOR] |
| Database: | Energy & Power Source |
| FullText | Text: Availability: 0 |
|---|---|
| Header | DbId: enr DbLabel: Energy & Power Source An: 194006685 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
| IllustrationInfo | |
| Items | – Name: Title Label: Title Group: Ti Data: Discrete modelling of ion diffusion in clays with overlapped electrical double layers. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Qu%2C+Yongxiao%22">Qu, Yongxiao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Bo%22">Li, Bo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+LiGe%22">Wang, LiGe</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yan%2C+Huaxiang%22">Yan, Huaxiang</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Bian%2C+Kang%22">Bian, Kang</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jivkov%2C+Andrey+P%2E%22">Jivkov, Andrey P.</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xiong%2C+Qingrong%22">Xiong, Qingrong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> qingrong.xiong@sdu.edu.cn</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Radioanalytical+%26+Nuclear+Chemistry%22">Journal of Radioanalytical & Nuclear Chemistry</searchLink>. May2026, Vol. 335 Issue 5, p3937-3951. 15p. – Name: Subject Label: Subject Terms Group: Su Data: *<searchLink fieldCode="DE" term="%22Electric+double+layer%22">Electric double layer</searchLink><br />*<searchLink fieldCode="DE" term="%22Debye+length%22">Debye length</searchLink><br />*<searchLink fieldCode="DE" term="%22Ion+migration+%26+velocity%22">Ion migration & velocity</searchLink><br />*<searchLink fieldCode="DE" term="%22Ion+mobility%22">Ion mobility</searchLink><br />*<searchLink fieldCode="DE" term="%22Clay%22">Clay</searchLink><br />*<searchLink fieldCode="DE" term="%22Van+der+Waals+forces%22">Van der Waals forces</searchLink><br />*<searchLink fieldCode="DE" term="%22Porosity%22">Porosity</searchLink><br />*<searchLink fieldCode="DE" term="%22Computer+simulation%22">Computer simulation</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The electrical double layer (EDL) critically influences ion transport prediction in clay, yet current models fail to accurately simulate diffusion in highly compacted clay across broad ionic strengths, especially low concentrations (e.g., 0.01 mol/L). This work proposes a robust model integrating a pore network approach with pore-specific ion transport. Pores are categorized into three types based on Debye length and EDL overlap degree. Van der Waals forces are incorporated for pores with severe EDL overlap. The numerical results predicted under a larger span of anion and cation concentration agree well with the experimental data. [ABSTRACT FROM AUTHOR] |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=enr&AN=194006685 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10967-026-10899-9 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 15 StartPage: 3937 Subjects: – SubjectFull: Electric double layer Type: general – SubjectFull: Debye length Type: general – SubjectFull: Ion migration & velocity Type: general – SubjectFull: Ion mobility Type: general – SubjectFull: Clay Type: general – SubjectFull: Van der Waals forces Type: general – SubjectFull: Porosity Type: general – SubjectFull: Computer simulation Type: general Titles: – TitleFull: Discrete modelling of ion diffusion in clays with overlapped electrical double layers. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Qu, Yongxiao – PersonEntity: Name: NameFull: Li, Bo – PersonEntity: Name: NameFull: Wang, LiGe – PersonEntity: Name: NameFull: Yan, Huaxiang – PersonEntity: Name: NameFull: Bian, Kang – PersonEntity: Name: NameFull: Jivkov, Andrey P. – PersonEntity: Name: NameFull: Xiong, Qingrong IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 05 Text: May2026 Type: published Y: 2026 Identifiers: – Type: issn-print Value: 02365731 Numbering: – Type: volume Value: 335 – Type: issue Value: 5 Titles: – TitleFull: Journal of Radioanalytical & Nuclear Chemistry Type: main |
| ResultId | 1 |
