A Simple and Fast Method for Investigating the Liquid-Vapor Equilibrium of the Water-Acetic Acid System

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Bibliographic Details
Title: A Simple and Fast Method for Investigating the Liquid-Vapor Equilibrium of the Water-Acetic Acid System
Language: English
Authors: Patricia Prodan, Matteo Neffat, Renato Bonomi (ORCID 0000-0002-0546-8492)
Source: Journal of Chemical Education. 2024 101(3):1268-1273.
Availability: Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Peer Reviewed: Y
Page Count: 6
Publication Date: 2024
Document Type: Journal Articles
Reports - Descriptive
Education Level: High Schools
Secondary Education
Descriptors: Chemistry, Science Instruction, Learning Activities, High School Students, Scientific Concepts, Science Experiments, Laboratory Experiments
DOI: 10.1021/acs.jchemed.3c01285
ISSN: 0021-9584
1938-1328
Abstract: The activity proposed in this study aims to investigate the equilibrium between the liquid and vapor phases in a mixture of water and acetic acid, both of which are volatile substances. High school students can easily determine the composition of the liquid phase and its corresponding vapor phase at equilibrium using a simple and conceptually clear method. This procedure allows for the construction of an "x/y" diagram that illustrates the trend of the compositions of the two phases at equilibrium. This experiment is performed at normal atmospheric pressure and requires no special equipment. It can be completed in a short 2 h laboratory session. Students then spend 3 h processing the experimental data. The results are then compared with theoretical values obtained using the Raoult-Dalton equation, combined with Antoine's or Clausius-Clapeyron's equation, and closely match the expected literature values.
Abstractor: As Provided
Entry Date: 2025
Accession Number: EJ1460222
Database: ERIC
Description
Abstract:The activity proposed in this study aims to investigate the equilibrium between the liquid and vapor phases in a mixture of water and acetic acid, both of which are volatile substances. High school students can easily determine the composition of the liquid phase and its corresponding vapor phase at equilibrium using a simple and conceptually clear method. This procedure allows for the construction of an "x/y" diagram that illustrates the trend of the compositions of the two phases at equilibrium. This experiment is performed at normal atmospheric pressure and requires no special equipment. It can be completed in a short 2 h laboratory session. Students then spend 3 h processing the experimental data. The results are then compared with theoretical values obtained using the Raoult-Dalton equation, combined with Antoine's or Clausius-Clapeyron's equation, and closely match the expected literature values.
ISSN:0021-9584
1938-1328
DOI:10.1021/acs.jchemed.3c01285