Unusual isotope effect in the reaction of chlorosilylene with trimethylsilane-1-d. Absolute rate studies and quantum chemical and Rice-Ramsperger-Kassel-Marcus calculations provide strong evidence for the involvement of an intermediate complex.

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Bibliographic Details
Title: Unusual isotope effect in the reaction of chlorosilylene with trimethylsilane-1-d. Absolute rate studies and quantum chemical and Rice-Ramsperger-Kassel-Marcus calculations provide strong evidence for the involvement of an intermediate complex.
Authors: Becerra R; Instituto de Quimica-Fisica Rocasolano, Consejo Superior de Investigaciones Científicas (CSIC), C/Serrano 119, 28006 Madrid, Spain. r.becerra@iqfr.csic.es, Boganov SE, Egorov MP, Krylova IV, Promyslov VM, Walsh R
Source: Journal of the American Chemical Society [J Am Chem Soc] 2012 Jun 27; Vol. 134 (25), pp. 10493-501. Date of Electronic Publication: 2012 Jun 14.
Publication Type: Journal Article
Journal Info: Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE
Database: MEDLINE Ultimate
Description
ISSN:1520-5126
DOI:10.1021/ja301924b