Unexpected cyclization of β-(hydroxymethyl)phosphole into 1-phospha-1,6a-dihydrophosphapentalene: a fused 1,3-butadiene-based luminophore.

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Title: Unexpected cyclization of β-(hydroxymethyl)phosphole into 1-phospha-1,6a-dihydrophosphapentalene: a fused 1,3-butadiene-based luminophore.
Authors: Higashino T; Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan. t-higa@scl.kyoto-u.ac.jp., Minobe R; Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan. t-higa@scl.kyoto-u.ac.jp., Machino T; Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan. t-higa@scl.kyoto-u.ac.jp., Imahori H; Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan. t-higa@scl.kyoto-u.ac.jp.; Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Kyoto, 606-8501, Japan.; Institute for Liberal Arts and Sciences (ILAS), Kyoto University, Kyoto, 606-8316, Japan.
Source: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2025 Jun 24; Vol. 61 (52), pp. 9420-9423. Date of Electronic Publication: 2025 Jun 24.
Publication Type: Journal Article
Journal Info: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9610838 Publication Model: Electronic Cited Medium: Internet ISSN: 1364-548X (Electronic) Linking ISSN: 13597345 NLM ISO Abbreviation: Chem Commun (Camb) Subsets: MEDLINE; PubMed not MEDLINE
Database: MEDLINE Ultimate
Description
ISSN:1364-548X
DOI:10.1039/d5cc02428e